N N-Dimethylformamide ACS Reagent 99.8% 4 Liter, case/4

$732.78

Part Number:MIL-437573-4X4L
Lead Time:2-4 weeks
Quantity:4
Size:4 liter / 1 gallon
Style:chemical
Description

N N-Dimethylformamide ACS Reagent ≥99.8% 4 Liter Case/4

Synonym: DMF, NSC 5356

  • CAS Number 68-12-2
  • Linear Formula HCON(CH3)2
  • Molecular Weight 73.09
  • Beilstein/REAXYS Number 605365
  • EC Number 200-679-5
  • MDL number MFCD00003284
  • PubChem Substance ID 24867382
Quality Level 200
Grade ACS reagent
Vapor Density 2.5 (vs air)
Vapor Pressure 2.7 mmHg (20°C)
Assay ≥99.8%
form liquid
Autoignition Temperature 833°F
Expl. Lim. 15.2 %
Impurities ≤0.0005 meq/g Titr. acid
≤0.003 meq/g Titr. base
≤0.15% water
Evaporation Residue ≤0.005%
Color APHA: ≤15
Refractive Index n20/D 1.430 (lit.)
bp 153°C (lit.)
mp −61°C (lit.)
solubility water: miscible
Density 0.944 g/mL (lit.)

General description

N,N-Dimethylformamide (DMF) is a polar organic solvent with a wide range of industrial applications. It is a precursor for numerous reactions such as formylation, aminocarbonylation, amination, amidation and cyanation. Along with phosphorus oxychloride, it forms Vilsmeier Reagent used in the formylation of reactive aromatic and heteroaromatic substrates. Dielectric relaxation experiments on DMF have been conducted between 238.15K and 338.15K. The thermophysical properties of the molecular interactions between DMF and the ionic liquids, ammonium salts and imidazolium salts have been studied. The characteristics of solute-solvent interactions between ammonium nitrate and DMF have been investigated.

Application

N,N-Dimethylformamide (DMF) may be used in the following processes:
• As a solvent synthesis of gold nanoparticles.
• As a solvent in capillary electrophoresis.
• Regioselective synthesis of N,N-dimethylaminopyridzines by reacting with choropyridazines.
• Synthesis of urea-N,N-dimethylformamide, a 3:1 solvate with urea.

Solvent for many hydrophobic organic compounds

GHS02, GHS07, GHS08

Signal word Danger
Hazard statements H226-H312 + H332-H319-H360D
Precautionary statements P201-P280-P305 + P351 + P338-P308 + P313
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RIDADR UN 2265 3 / PGIII
WGK Germany 2
RTECS LQ2100000
Flash Point(F) 136.4°F
Flash Point(C) 58°C

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